This is in agreement with experimental reports that demonstrate that pNBD spontaneously grafts at 100% sp 3 surfaces, 30,72 and indicates that pNBD attachment is possible, albeit at a slow rate, even at low sp 2 content. A first conclusion that emerges from Figure 7 is that a-C:H2 samples, despite having only a very small sp 2 content, still show a significant rate of attachment. It is clear from this graph that there is a strong dependence of the pNBD initial attachment rate on sp 2 content. The relative rate of adsorption at GC, which consists of 100% sp 2 carbon, was obtained from the ex situ electrochemical measurements in Figure 5.
Figure 7 shows a summary of the initial rates of pNBD deposition, relative to that at a-C:H2, at the four different carbon surfaces used in our experiments the plot shows the dependence of rates vs. Get your Fenty Beauty’s best-selling foundation at sephora.18 The relation between sp 2 content and reaction rates is of greater complexity.
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